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91.
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93.
Carbon isotope geochemistry of the Precambrian Lomagundi carbonate province,Rhodesia 总被引:1,自引:0,他引:1
Manfred Schidlowski Rudolf Eichmann Christian E. Junge 《Geochimica et cosmochimica acta》1976,40(4):449-455
Carbon isotope measurements carried out on 67 dolomite samples from the Middle Precambrian Lomagundi Group (Rhodesia) have yielded a δ13C mean of +8.2 ± 2.6%. vs PDB. With the outcrop of these dolomites extending over a distance of almost 300 km, the Lomagundi dolomite faces is likely to represent the largest isotopically anomalous sedimentary carbonate province ever recorded. It is concluded that the anomalous carbonates formed in a closed basin whose δ13C level had been substantially increased as a result of a preferential removal (within sedimentary organics) of the light carbon isotope. 相似文献
94.
Numerical modeling of the terrestrial oxygen budget based on the revised δ13Ccarb record by Veizeret al. (1980) has shown that total photosynthetic oxygen has varied between ±7% and ±10% of its average reservoir size (~3.2 × 1022 g) during the last 800 myr as a result of oscillations of the sedimentary reservoir of organic carbon. Calculated curves of oxygen evolution display a distinct minimum in the Early Paleozoic framed by two maxima in the Latest Proterozoic and the Mesozoic. The sympathetic relationship observed between the curves of total oxygen evolution and respective functions for the partial reservoir of sulfate-bound oxygen suggests that the O2 required for an additional conversion of sulfide to sulfate was most probably provided by excess burial of organic carbon, the results of the modeling thus adding credence to current interpretations proposed for the negative correlation between the secular and trends. 相似文献
95.
96.
Manfred Koch 《Tectonophysics》1982,90(1-2)
A study of the shallow and intermediate depth seismicity of the Romanian Vrancea region in the period 1964–1981 has been performed. The seismic events have been relocated by a standard location procedure using a regional velocity model. From the temporal and spatial distribution of the seismic activity, aspects of the seismicity before the large March 4, 1977 earthquake are treated, in particular the seismic gap in space and time prior to this event, found by Mârze (1979), which is critically discussed and revised. The concept of the precursor time/magnitude relationships of different authors is applied and its validity to the Vrancea region assessed. The hypocentral distribution shows that the intermediate depth seismic activity is confined to a small volume with dimensions of only some tens of kilometers. The results are interpreted in terms of the tectonics of the region. From an analysis of the travel-time residuals at different local stations, evidence for lateral velocity heterogeneities beneath the region is obtained e.g. a high velocity zone southeastwards of the Carpathian chain. Finally mean
ratios, (i.e. Poisson's ratios), for various stations are calculated from P- and S-wave travel times. They show azimuthal variations of up to 6% for stations within the area where the intermediate seismic activity occurs in comparison with the station Focsani, situated eastwards in the Carpathian foredeeps. All these results are compatible with the plate tectonic concept for the Vrancea region, that is the subduction of an oceanic lithospheric slab under the Carpathian mountain arc, giving rise to such a highly active seismic zone. 相似文献
97.
98.
Manfred Schidlowski 《Precambrian Research》1983,20(2-4)
Current photochemical models suggest that oxygen levels in the prebiological atmosphere were extremely low, most probably remaining in the range 10−8–10−14 PAL (present atmospheric level). It is, therefore, reasonable to assume that only life processes were able to overwhelm these minor O2-pressures, with free oxygen resulting from the reduction of carbon dioxide to the carbohydrate level during photoautotrophic carbon fixation using water as an electron donor (
). It is by now well established that reduced (organic) carbon is a common constituent of sedimentary rocks from the very start of the geological record 3.8 Ga ago. Both direct assays and inferences derived from a carbon isotope mass balance suggest that the Corg-content of Archaean sediments was not basically different from that of geologically younger rocks. This poses the problem of the existence 3.5 Ga ago of an oxidation equivalent of such a formidable ancient Corg-reservoir which, depending on the model adopted for the growth of the sedimentary mass through time, might have amounted to between 20 and 100% of the present one. Low atmospheric oxygen pressures in the Early Precambrian that are inferred from retarded oxidation reactions, notably in the ancient continental weathering cycle, are likely, therefore, to indicate extremely rapid processes of oxygen consumption in other parts of the system (e.g., hydrosphere) rather than the general absence of photosynthetic oxidation equivalents during this time. 相似文献
Full-size image (1K)
99.
Orbell JD Ngeh LN Bigger SW Zabinskas M Zheng M Healy M Jessop R Dann P 《Marine pollution bulletin》2004,48(3-4):336-340
Iron powder, a promising dry-cleansing agent for oiled feathers where both the contaminant and the cleansing agent may be harvested magnetically, has been tested on the plumage of whole-bird models. The breast and back plumage of Mallard Duck (Anas platyrhynchos) and Little Penguin (Eudyptula minor) carcasses were patch-contaminated with commercial-grade engine oil, three different crude oils, and an oil/seawater emulsion. The plumage was then subjected to a magnetic cleansing protocol. The contaminant removal was assessed gravimetrically and was found to reflect the outcomes for a previously reported in vitro study using feather clusters. Between 92-98% of the contaminants, and effectively all of the cleansing agent, were removed from the feathers. 相似文献
100.
Amarasooriya?PitawalaEmail author Manfred?Schidlowski Kapila?Dahanayake Wolfgang?Hofmeister 《Mineralium Deposita》2003,38(4):505-515
The apatite-bearing carbonate rocks at Eppawala, Sri Lanka occur as massive, discontinuous bodies in a Precambrian, high-grade metamorphic terrain, which weather to form economically important phosphate deposits. The ore bodies at Eppawala contain =42% P 2O 5, and citric acid solubility of different components varies from 4 to 6%. The parent rocks are mainly made up of calcite, dolomite and apatite, with lesser amounts of ilmenite, magnetite, pyrite, forsterite, phlogopite, enstatite, magnesite, diopside, tremolite and spinel. Most of minerals show an euhedral habit, with a wide range of crystal sizes (from a few millimetres to several decimetres). The Eppawala rocks are characterised by low silica (=0.41%), high phosphorous (=10.58%) and high strontium content (2,960–6,819 ppm). Concentrations of light rare-earth elements in these rocks are comparably higher than those of marbles. The REE fractionation of these rocks is pronounced, and La/Yb ratios vary between 14 and 43. Both apatite and calcite show markedly elevated strontium levels (=0.6%). The d 13C PDB and d 18O SMOW values of the carbonates are in the range of –3.4 to –2.2 and 7.7 to 16.4‰ respectively. The euhedral habit, as well as the presence of major quantities of apatite and considerable amounts of iron-bearing minerals suggest that the ore host rock has genetic links to an igneous source rather than to an intensely metamorphosed limestone. The higher light REE contents of the rocks, compared to marbles, also argue against a metamorphic or sedimentary origin. The Sr/Mn and Ce/La ratios in the apatite are ~40 and ~2 respectively, suggesting that they were formed in a carbonatite magma. The markedly increased REE concentrations in the bulk chemistry of the rocks have been shown to be mainly controlled by the content of phosphate minerals. Compared to most carbonatites, the Eppawala rocks are generally depleted in selected trace elements, particularly Ba, Nb, Th, V, U and Zr. This depletion may be due to either a primary infertility of the parent magma with regard to such trace elements, or it is a result of fractional crystallisation during the rock formation. The stable isotope ratios do not plot within the defined "mantle carbonatite box", but still lie within the broader range of carbonatitic rocks. With these data at hand, it can be readily argued that the mode of occurrence, petrography and geochemistry of the Eppawala apatite-bearing carbonates provide conclusive evidence of their carbonatitic origin. 相似文献